
Anhydrite conversion to dihydrate gypsum
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416 Dissolution and Conversions of Gypsum and Anhydrite
Gypsum dissolves by a simple twophase dissociation Anhydrite, when dissolved, forms a solution of calcium sulfate, which at common temperatures and pressures is in equilibrium with 2019年4月30日 The dehydration products of gypsum under different temperature and water vapor pressure were investigated by thermodynamic theory Additionally, the rehydration mechanism of soluble anhydrite(PDF) Dehydration Pathways of Gypsum and the 2019年4月26日 The apparent empirical activation energies (Ea) suggest that the transition from gypsum to hemihydrate is mainly controlled by nucleation and growth mechanism, while the transition from gypsum to γanhydrite is mostly Dehydration Pathways of Gypsum and the Rehydration anhydrite into gypsum crystals This transformation takes place via the solution phase, ie via anhydrite dissolution and gypsum precipitation The chemical dissolution and precipitation The Solubilities and Thermodynamic Equilibrium of Anhydrite and

The dissolution and conversion of gypsum and anhydrite
Gypsum and anhydrite are both soluble minerals forming rocks that can dissolve at surface and underground resulting in sulphate karst causing geological hazards, especially subsidence and 2011年6月1日 Below 100 °C, the mechanism consists of a direct dehydration step of gypsum to anhydrite (with no intermediate hemihydrate formation), resulting in the formation of anhydrite Mechanism and kinetics of gypsum–anhydrite ScienceDirect2014年10月29日 We show that intrinsic thermodynamic and kinetic properties severely constrain the precipitation of anhydrite (compared to gypsum and bassanite), and consequently, a The gypsum–anhydrite paradox revisited ScienceDirect2024年6月15日 The phase transformation of anhydrite III to anhydrite II, occurring between 350 and 500 °C, caused significant shrinkage, as showed by TD, because anhydrite II has a New insight into the phase changes of gypsum
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Dissolution and conversions of gypsum and anhydrite
Gypsum dissolves by a simple twophase dissociation Anhydrite, when dissolved, forms a solution of calcium sulfate, which at common temperatures and pressures is in equilibrium with the solid phase of gypsum, but not with anhydriteThe development of karst is a complex system driven by the dissolution of a host rock and the subsequent removal of dissolved matter by moving water It is the process that, at various stages, initiates or triggers associated processes including erosion, collapse and subsidence The dissolution of sulphate rocks proceeds by different mechanisms and at different rates to those The dissolution and conversion of gypsum and anhydrite2011年6月1日 Calcium sulfate can be precipitated as dihydrate (DH) or gypsum (CaSO 4 2H 2 O) at low temperatures and as hemihydrate (HH) (CaSO 4 05H 2 O) or anhydrite (AH) (CaSO 4) at elevated temperatures (Li and Demopoulos, 2005)All calcium sulfate hydrates are relatively insoluble and they are formed wherever calcium and sulfate occur together after the Mechanism and kinetics of gypsum–anhydrite ScienceDirect2013年1月1日 Anhydrite (CaSO 4) and gypsum (CaSO 4 2H 2 O) are the two most abundant minerals of ancient marine evaporite deposits and are also common in nonmarine evaporite deposits Sedimentary gypsum forms by direct precipitation out of evaporating seawater under arid climatic conditions in hydrologically restricted marine and marginal marine environments Anhydrite and gypsum SpringerLink
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Solubility Measurements and Predictions of Gypsum, Anhydrite,
2016年11月4日 Today’s oil and gas production from deep reservoirs permits exploitation of more oil and gas reserves but increases risks due to conditions of high temperature and high pressure Predicting mineral solubility under such extreme conditions is critical for mitigating scaling risks, a common and costly problem Solubility predictions use solubility products and activity 2009年11月20日 Gypsum vs Anhydrite Gypsum, also called hydrated calcium sulphate (CaSO4 Â 2H2O) and anhydrite (CaSO4), also called hydrous calcium sulphate are the major minerals in the sedimentary rocks of rock gypsum and rock anhydrite respectively Gypsum consists of calcium, sulfur and water while anhydrite consists of calcium, sulfur and oxygenDifference Between Gypsum and Anhydrite2023年5月15日 Gypsum is one of the most widelyused building materials in the world It is applied in several interior building uses, including in wallboard Normally, calcium sulphate dihydrate (CaSO 4 •2H 2 O) is used as a raw material and a subhydrate such as hemihydrate (CaSO 4 •05H 2 O) or anhydrite (CaSO 4) is producedUnderstanding gypsum in 3 diagrams2019年4月30日 The dehydration products of gypsum under different temperature and water vapor pressure were investigated by thermodynamic theory Additionally, the rehydration mechanism of soluble anhydrite was (PDF) Dehydration Pathways of Gypsum and the Rehydration Mechanism

Evidence of a new phase in gypsum–anhydrite transformations
2020年9月17日 Abstract Mineral transformations of the gypsum–anhydrite system under microwave heating have been studied using in situ dielectric thermal analysis (MWDETA) and Raman spectroscopy simultaneously The dielectric properties of samples that were measured under microwave heating provided thorough information about the dynamics of the 2023年9月20日 Thus, a longstanding discussion about the thermodynamic aspect of the gypsumanhydrite conversion can be closed, not the kinetic part 1 Introduction Calcium sulfate occurs in several forms: as dihydrate (mineral: gypsum), as hemihydrate (mineral: bassanite) and anhydrous (mineral: anhydrite)Frontiers Solubility of anhydrite and gypsum at temperatures Main Differences Between Gypsum and Anhydrite Gypsum is a mineral that is aqueous and contains 2 water molecules, while anhydrite, as it is known, is an anhydrous mineral and does not contain water molecules The chemical formula of gypsum is (CaSO4 2H2O) On the other hand, the chemical formula of anhydrite is (CaSO4) Gypsum is softer Gypsum vs Anhydrite: Difference and Comparison2018年9月12日 Anhydrite was first discovered in 1794 in the Hall salt mine near Innsbruck, Austria, and named then or shortly after by Abraham Gottlob Werner The depth of the occurrence was critical to the discovery, because nearer the Anhydrite the Dry Gypsum MineralExpert

Anhydrite and gypsum SpringerLink
However, laboratory evidence for the synthesis of anhydrite directly from NaClrich waters has shown that gypsum is always the stable phase () Hardie (1967) converted gypsum to anhydrite in solutions containing high concentrations of H 2 SO 4, and Cruft and Chao (1969) showed that under conditions of very high supersaturation, ie, high Ca 2+ or high SO 4 2−, anhydrite 2022年12月8日 Gypsum (calcium sulfate dihydrate) is one of the most used inorganic binding materials in the world During calcination, calcium sulfate subhydrates are formed and, for technical reasons, are mixed with water to Formation of alpha;Hemihydrate Inside of a 2014年10月29日 Conversion of gypsum to anhydrite in aqueous salt solutions Geochim Cosmochim Acta, 23 (1964), pp 13631372 A new precipitation pathway for calcium sulfate dihydrate (gypsum) via amorphous and hemihydrate intermediates Chem Commun, 48 (2012), pp 504506 View in Scopus Google Scholar Warren, 2006The gypsum–anhydrite paradox revisited ScienceDirect2016年7月1日 Analysis of the data shows distinct areas of similarity separated by the conversion to anhydrite ∼250 °C Fe3+, and Cr3+ ions on crystallization of calcium sulfate dihydrate (gypsum) Thermal Analysis of Calcium Sulfate Dihydrate Sources Used to

Thermal analysis of calcium sulfate dihydrate sources used to
2016年9月10日 Gypsum wallboard has been used for over 100 years as a barrier to the spread of fire in residential and commercial structures The gypsum molecule, CaSO 4 2H 2 O, provides two crystalline waters that are released upon heating providing an endothermic effect Manufacturers have recognized that the source of the gypsum ore is a factor that affects all 2019年4月26日 The dehydration products of gypsum under different temperature and water vapor pressure were investigated by thermodynamic theory Additionally, the rehydration mechanism of soluble anhydrite was also studied by Monte Carlo the occurrence of a twostep conversion path CaSO 4 2H 2 O → βCaSO 4 05H 2 O → γCaSO 4 was Dehydration Pathways of Gypsum and the Rehydration Mechanism 2023年11月23日 Gypsum, a widely used mineral, is known for its softness and is composed of calcium sulfate dihydrate Anhydrite, on the other hand, is a hard mineral, the anhydrous form of calcium sulfate, and is often found in salt depositsGypsum vs Anhydrite: What’s the Difference?2023年10月27日 Gypsum is a hydrated calcium sulfate mineral used in construction and agriculture, while anhydrite is its dehydrated form, harder and used in cement Gypsum is a soft mineral composed of calcium sulfate dihydrate Anhydrite is also a calcium sulfate mineral, but it lacks water molecules 15 Gypsum has a variety of uses, from Gypsum vs Anhydrite — What’s the Difference?

The Solubilities and Thermodynamic Equilibrium of Anhydrite and Gypsum
2014年2月25日 Anhydritic claystones consist of a clay matrix with finely distributed anhydrite Their swelling has led to severe damage and high repair costs in several tunnels Gypsum growth combined with water uptake by the clay minerals is the main cause of the swelling process Identifying the conditions under which gypsum rather than anhydrite represents the stable Anhydrite gypsum and dihydrate gypsum have the same solubility in water at normal temperatures—2531 gr/L at 20°C— meaning that water can hold the same amount of calcium sulfate in solution, no matter which source it comes from1309 Which Gypsum: Anhydrite or Dihydrate? Best Soil 2022年4月1日 Plaster, made of calcium sulfate hemihydrate (CaSO 4 •½H 2 O) and/or γanhydrite (CaSO 4) is obtained by dehydration of gypsum (CaSO 4 2H 2 O) at 100–200 °C When mixed with water, it dissolves while new gypsum crystals precipitate Plaster's microstructures affect its reactivity and setting properties, but are poorly understood due to From atom level to macroscopic scale: Structural mechanism of gypsum 2014年10月29日 Conversion of gypsum to anhydrite in aqueous salt solutions Geochim Cosmochim Acta (1964) Role and fate of the lead during the conversion of calcium sulfate dihydrate to αhemihydrate whiskers in ethylene glycolwater solutions Chemical Engineering Journal, Volume 372, 2019, pp 7481The gypsum–anhydrite paradox revisited ScienceDirect

THE STABILITY OF GYPSUM AND ANHYDRITE Massachusetts
STABILITY OF GYPSUM AND ANHYDRITE IN THE GEOLOGIC ENVIRONMENT by LEONARD STEVEN ROLNICK AB, THE JOHNS HOPKINS UNIVERSITY PRESSURETEMPERATURE CONVERSION DATA 94 IX DRILLHOLE LOGS Gypsum is composed of calcium sulphate dihydrate (CaSO42H20) and has the very useful property of being converted to the 2007年12月1日 Download Citation The dihydrate‐hemihydrate transformation in gypsum A microscope study has been made of the development of crystals of calcium sulphate hemihydrate produced on, or in The dihydrate‐hemihydrate transformation in gypsumAGRICULTURAL GYPSUM Dihydrate vs Anhydrite The highest quality gypsum for agriculture is natural, a dihydrate, has beneficial trace minerals, and purity levels over 80% Because Dihydrate is already hydrated with water molecules, as opposed to anhydrite, it dissolves faster in water If dissolved in the irrigation water, dissolution speed has little effect; however, when applied []Dihydrate vs Anhydrite Pink Gypsum2022年10月16日 Calcium sulfate exists in three forms, namely dihydrate or gypsum (CaSO42H2O), anhydrite (CaSO4), and hemihydrate or bassanite (CaSO405H2O) depending on temperature, pressure, pH, and formation conditions The formation of calcium sulfates occurs widely in nature and in many engineering settings Herein, a dataset containing the Experimental Data on Solubility of the Two Calcium Sulfates Gypsum

(IUCr) A kinetic and mechanistic study into the transformation
2019年2月2日 To speed up the conversion from hemihydrate to dihydrate, seed crystals of gypsum are generally added to a mixture of stucco and water; these are thought to provide extra nucleation sites, and have the additional benefit of improving the hardness of the plaster (Amathieu Boistelle, 1986)anhydrite into gypsum crystals This transformation takes place via the solution phase, ie via anhydrite dissolution and gypsum precipitation The chemical dissolution and precipitation reactions of gypsum and anhydrite are CaSO 4 2H 2O $ Ca2þ þ SO2 4 þ 2H 2O ð1Þ and CaSO 4 $ Ca2þ þ SO2 4; ð2Þ respectivelyThe Solubilities and Thermodynamic Equilibrium of Anhydrite and Gypsum2016年9月10日 Analysis of the data shows distinct areas of similarity separated by the conversion to anhydrite ∼250 that the treatment process does not affect the amorphousity and phase composition of LS except for the disappearance of gypsum (calcium sulfate dihydrate, CaSO42H2O) in TS as gypsum decomposed at 250 °C as well as an increase Thermal analysis of calcium sulfate dihydrate sources used to DISSOLUTION AND CONVERSIONS OF GYPSUM AND ANHYDRITE 030 026 020 015 010 005 Fig 3 Solubility Of gypsum and drite in water al one atmosphere re (after 7wnhY,lk Arthur, 1986) Gypsum The dissolution and conversion of gypsum and anhydrite

Quantitative determination of anhydrite III from dehydrated gypsum
2009年10月1日 Secondary anhydrite formation may take place by either dehydration of gypsum to bassanite and γanhydrite, phase transformation to βanhydrite (Christensen et al, 2008; Seufert et al, 2009 2005年4月1日 In this context, Sievert et al [86] confirmed the conversion of anhydrite into gypsum during hydration when anhydrite is exposed to a water source and water molecules enter through the cracks of Hydration of anhydrite of gypsum (CaSO 4II) in a ball millFast, continuous conversion of dihydrate gypsum to alpha gypsum hemihydrate is desirable The ability to produce large quantities at a rapid rate is needed in the industry Upon further loss of water, gypsum anhydrite is produced according to the following chemical equation: CaSO 405H 2 O+heat→CaSO 4 +05H 2 OProcess for producing alphahemihydrate gypsum Google Gypsum and gypsum plaster products can be made from an anhydrite or mixed anhydrite and gypsum starting material, of natural origin or derived chemically as a byproduct, by mixing the powdered anhydrite with part or all (but not more) of the water necessary for complete hydration to gypsum, compressing the mixture into compacted blocks or other bodies, and allowing the Process for the conversion of anhydrite into gypsum

Gypsum vs Anhydrite: Know the Difference
2024年1月10日 Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, whereas anhydrite is its anhydrous form Home; New; Gypsum vs Anhydrite: Know the Difference and anhydrite can rehydrate to form gypsum under the right conditions, highlighting their close relationship 5 Shumaila Saeed Jan 10, 20242020年1月14日 石膏(Gypsum)、硬石膏(Anhydrite)一、概述石膏、硬石膏这两种矿物主要是盐湖中化学沉积作用的产物,常与石盐、钾盐及光卤石共生。两种石膏常伴生产出,又可互相转化(表3181及表3182)。通常所称石膏矿或石膏(Gypsum)、硬石膏(Anhydrite) 百度知道Both gypsum (Calcium Sulfate Dihydrate) and anhydrite (Calcium Sulfate) have the same solubility of 0205 grams per 100 grams water (2019 CRC Handbook of Chemistry and Physics) This has also been verified by many field trials by soil Quality Gypsum Calcium Sulfate Dihydrate Farming Gypsum 2023年7月3日 Flue gas desulfurization (fgd) is a waste incineration process that employs limestone slurry (CaCO 3) as a scrubber to remove SO 2 from exhaust gases, thereby reducing pollutant emissions CaCO 3 reacted with SO 2 to form calcium sulphite (CaSO 3), which was then oxidized to form anhydrite (CaSO 4) and gypsum (CaSO 4 ⋅2H 2 O), also known as fgd The Mechanochemical Process and H2SO4 Treatment on the
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Modeling gypsum (calcium sulfate dihydrate) solubility in
2024年1月1日 The most prevalent sulfate mineral in the surrounding natural environment is calcium sulfate, which can be found as calcium sulfate dihydrate or gypsum (CaSO 4 2H 2 O), hemihydrate (CaSO 4 ½H 2 O), and anhydrite (CaSO 4) All of these forms have the ability to be crystallized in the presence of water [11, 12]